The RbSr (2)Sigma(+) ground state investigated via spectroscopy of hot and ultracold molecules
Authors: Ciamei A., Szczepkowski J., Bayerle A., Barbe V., Reichsollner L., Tzanova S.M., Chen C.C., Pasquiou B., Grochola A., Kowalczyk P., Jastrzebski W., Schreck F.
Autors Affiliation: 1)Univ Amsterdam, Van der Waals Zeeman Inst, Inst Phys, Sci Pk 904, NL-1098 XH Amsterdam, Netherlands
2)Polish Acad Sci, Inst Phys, Al Lotnikow 32-46, PL-02668 Warsaw, Poland
3)Austrian Acad Sci, Inst Quantenopt & Quanteninformat IQOQI, A-6020 Innsbruck, Austria
4)Univ Warsaw, Inst Expt Phys, Fac Phys, Ul Pasteura 5, PL-02093 Warsaw, Poland
5)ARCNL, Sci Pk 110, NL-1098 XG Amsterdam, Netherlands
Abstract: We report on spectroscopic studies of hot and ultracold RbSr molecules, and combine the results in an analysis that allows us to fit a potential energy curve (PEC) for the X(1)(2)Sigma(+) ground state bridging the short-to-long-range domains. The ultracold RbSr molecules are created in a mu K sample of Rb and Sr atoms and probed by two-colour photoassociation spectroscopy. The data yield the long-range dispersion coefficients C-6 and C-8, along with the total number of supported bound levels. The hot RbSr molecules are created in a 1000 K gas mixture of Rb and Sr in a heat-pipe oven and probed by thermoluminescence and laser-induced fluorescence spectroscopy. We compare the hot molecule data with spectra we simulated using previously published PECs determined by three different ab initio theoretical methods. We identify several band heads corresponding to radiative decay from the B(2)(2)Sigma(+) state to the deepest bound levels of X(1)(2)Sigma(+). We determine a mass-scaled high-precision model for X(1)(2)Sigma(+) by fitting all data using a single fit procedure. The corresponding PEC is consistent with all data, thus spanning short-to-long internuclear distances and bridging an energy gap of about 75% of the potential well depth, still uncharted by any experiment. We benchmark previous ab initio PECs against our results, and give the PEC fit parameters for both X(1)(2)Sigma(+) and B(2)(2)Sigma(+) states. As first outcomes of our analysis, we calculate the s-wave scattering properties for all stable isotopic combinations and corroborate the locations of Fano-Feshbach resonances between alkali Rb and closed-shell Sr atoms recently observed [V. Barbe et al., Nat. Phys., 2018, 14, 881]. These results and more generally our strategy should greatly contribute to the generation of ultracold alkali-alkaline-earth dimers, whose applications range from quantum simulation to state-controlled quantum chemistry.
Journal/Review: PHYSICAL CHEMISTRY CHEMICAL PHYSICS (PRINT)
Volume: 20 (41) Pages from: 26221 to: 26240
KeyWords: PHOTOASSOCIATION SPECTROSCOPY; SCATTERING; CHEMISTRY; MATTER; ATOMS; GASDOI: 10.1039/c8cp03919dCitations: 18data from “WEB OF SCIENCE” (of Thomson Reuters) are update at: 2022-12-04References taken from IsiWeb of Knowledge: (subscribers only)Connecting to view paper tab on IsiWeb: Click hereConnecting to view citations from IsiWeb: Click here